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Glycogenolysis is a metabolic process that converts glycogen from the muscles and liver to its monosaccharide form, glucose. Glycogen is a glucose polysaccharide stored in the muscles and liver. Glycogenolysis is the breakdown of complex carbohydrate glycogen into glucose-1-phosphate, which may then be changed into glucose-6-phosphate and enter the glycolytic pathway to make ATP. Degradation of stored glycogen, termed glycogenolysis , occurs through one of two pathways, cytosolic and lysosomal. The cytosolic pathway involves the actions of glycogen phosphorylase (GP; often referred to simply as phosphorylase) and the glycogen debranching enzyme (GDE). Glycogenolysis is the breakdown of glycogen into glucose for energy. Learn where it occurs, how it works, and its functions and abnormalities.